使用负载型金和碱作为催化剂，通过醇或醛与胺的有氧氧化偶联一锅法合成酰胺。
One-pot synthesis of amides by aerobic oxidative coupling of alcohols or aldehydes with amines using supported gold and base as catalysts.
机构信息
Centre for Catalysis and Sustainable Chemistry, Department of Chemistry, Technical University of Denmark, Building 207, 2800 Kgs. Lyngby, Denmark.
出版信息
Chem Commun (Camb). 2012 Feb 28;48(18):2427-9. doi: 10.1039/c2cc16768a. Epub 2012 Jan 25.
PMID:22274843
Abstract
Synthesis of amides by aerobic oxidative coupling of alcohols or aldehydes with amines via intermediate formation of methyl esters is highly efficient and selective when using a catalytic system comprised of supported gold nanoparticles and added base in methanol.
摘要
当使用负载型金纳米粒子和添加的碱组成的催化体系在甲醇中时，醇或醛与胺通过中间甲酯的形成进行有氧氧化偶联合成酰胺是高效和选择性的。
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