NHC 催化的非活化醛的高选择性有氧氧化。
NHC-catalysed highly selective aerobic oxidation of nonactivated aldehydes.
机构信息
TU-Berlin - Berlin Institute of Technology, Institute of Chemistry, Straße des 17. Juni 115, 10623 Berlin, Germany. ; Tel:(+49)-30-314-22255.
出版信息
Beilstein J Org Chem. 2013 Mar 22;9:602-7. doi: 10.3762/bjoc.9.65. Print 2013.
Abstract
This publication describes a highly selective oxidation of aldehydes to the corresponding acids or esters. The reaction proceeds under metal-free conditions by using N-heterocyclic carbenes as organocatalysts in combination with environmentally friendly oxygen as the terminal oxidation agent.
摘要
本出版物介绍了一种醛的高选择性氧化为相应的酸或酯的方法。该反应在无金属条件下进行，使用 N-杂环卡宾作为有机催化剂，并结合环保的氧气作为末端氧化剂。
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