模拟沸石的核心：多孔方钠石笼作为悬挂的三聚体 M3(OH)簇（M = Mg、Mn、Co、Ni、Cd）的支架。
Mimicking zeolite to its core: porous sodalite cages as hangers for pendant trimeric M3(OH) clusters (M = Mg, Mn, Co, Ni, Cd).
机构信息
Department of Chemistry and Biochemistry, California State University, Long Beach, California 90840, USA.
出版信息
J Am Chem Soc. 2012 Feb 1;134(4):1934-7. doi: 10.1021/ja209800x. Epub 2012 Jan 19.
PMID:22280215
Abstract
A new class of zeolite-type porous materials in which 3D frameworks are covalently functionalized with crystallographically ordered pendant metal clusters have been synthesized. This work demonstrates a new paradigm for and the feasibility of functionalizing zeolite-type frameworks through the conversion of extraframework sites in mineral zeolites into part of the framework for occupation by dangling metal clusters in metal-organic frameworks.
摘要
一类新型沸石型多孔材料已经被合成，其三维骨架通过结晶有序的悬挂金属簇进行共价功能化。这项工作展示了一种新的范例和可行性，即通过将矿物沸石中的骨架外位点转化为金属有机骨架中悬挂金属簇占据的部分骨架，从而对沸石型骨架进行功能化。
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