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微浮选在藻分离中的性能。

Microflotation performance for algal separation.

机构信息

Department of Chemical and Biological Engineering, University of Sheffield, Mappin Street, Sheffield S1 3JD, United Kingdom.

出版信息

Biotechnol Bioeng. 2012 Jul;109(7):1663-73. doi: 10.1002/bit.24449. Epub 2012 Jan 30.

Abstract

The performance of microflotation, dispersed air flotation with microbubble clouds with bubble size about 50 µm, for algae separation using fluidic oscillation for microbubble generation is investigated. This fluidic oscillator converts continuous air supply into oscillatory flow with a regular frequency to generate bubbles of the scale of the exit pore. Bubble characterization results showed that average bubble size generated under oscillatory air flow state was 86 µm, approximately twice the size of the diffuser pore size of 38 µm. In contrast, continuous air flow at the same rate through the same diffusers yielded an average bubble size of 1,059 µm, 28 times larger than the pore size. Following microbubble generation, the separation of algal cells under fluidic oscillator generated microbubbles was investigated by varying metallic coagulant types, concentration and pH. Best performances were recorded at the highest coagulant dose (150 mg/L) applied under acidic conditions (pH 5). Amongst the three metallic coagulants studied, ferric chloride yielded the overall best result of 99.2% under the optimum conditions followed closely by ferric sulfate (98.1%) and aluminum sulfate with 95.2%. This compares well with conventional dissolved air flotation (DAF) benchmarks, but has a highly turbulent flow, whereas microflotation is laminar with several orders of magnitude lower energy density.

摘要

采用射流振荡器产生微气泡的微浮选和分散空气浮选的性能研究,其中微气泡云的气泡尺寸约为 50 µm。这种射流振荡器将连续的空气供应转换为具有规则频率的振荡流,以产生与出口孔径相当的气泡。气泡特性研究结果表明,在振荡气流状态下产生的平均气泡尺寸为 86 µm,大约是 38 µm 扩散器孔径的两倍。相比之下,以相同的速率通过相同的扩散器连续供应空气会产生平均气泡尺寸为 1059 µm 的气泡,比孔径大 28 倍。在微气泡产生之后,通过改变金属凝结剂的类型、浓度和 pH 值,研究了在射流振荡器生成的微气泡下藻类细胞的分离情况。在酸性条件(pH 5)下施加最高凝结剂量(150 mg/L)时,记录到最佳性能。在所研究的三种金属凝结剂中,三氯化铁在最佳条件下产生了 99.2%的整体最佳效果,紧随其后的是硫酸铁(98.1%)和硫酸铝(95.2%)。这与传统的溶解空气浮选(DAF)基准相比表现良好,但具有高度的湍流,而微浮选是层流的,能量密度低几个数量级。

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