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[广西壮族自治区某金属冶炼厂废水排放对农业土壤的污染]

[Pollution of agricultural soils by a wastewater outflow from a metal smelter in Guangxi Zhuang autonomous region].

作者信息

Yuan Yong-Qiang, Liu Cong-Qiang

机构信息

State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002, China.

出版信息

Huan Jing Ke Xue. 2011 Nov;32(11):3312-7.

Abstract

Pollution characteristics of heavy metals in the farmland soil nearby a metal smelter were studied. Soil samples were collected and the contents of elements V, Cr, Mn, Co, Ni, Cu, Zn, Rb, Sr, Mo, Cd, Sn, Sb, Pb, U and As in the bulk samples of soil profiles were measured, with the objectives to identify the pollution status and pollution characteristics of the farmland soil that were suffered from smelter effluents flooding, an acute pollution accident. The results indicate that the concentrations of heavy metals Zn, Mn, As, Pb, Cd,Sb in the soil were 113.28-212.22, 251.67-2 429.29, 34.44-130.28, 50.63-544.74, 63.44-317.33, 39.41-551.17 mg/kg, respectively, higher than the background level. These polluted soils not only have high concentrations of As, but also of the Zn, Mn, Pb, Cd and Sb. According to correlation analysis, pollution level is closely with local nonferrous metal exploitation, and principal pollutants have the same source. Some trace metals, such as Zn, Cr, Cd, show increasing concentration first and then decreasing trend in the soil profile. Soil acidification appears in the topsoil. This study has characterized the metal pollution in soils flooded by sudden smelting effluents spilling, and provided a theory base for pollution treatment.

摘要

研究了某金属冶炼厂附近农田土壤中重金属的污染特征。采集了土壤样本,测定了土壤剖面原状土样中V、Cr、Mn、Co、Ni、Cu、Zn、Rb、Sr、Mo、Cd、Sn、Sb、Pb、U和As等元素的含量,旨在确定遭受冶炼厂废水漫溢这一急性污染事故影响的农田土壤的污染状况和污染特征。结果表明,土壤中重金属Zn、Mn、As、Pb、Cd、Sb的含量分别为113.28 - 212.22、251.67 - 2429.29、34.44 - 130.28、50.63 - 544.74、63.44 - 317.33、39.41 - 551.17 mg/kg,均高于背景值。这些污染土壤不仅As含量高,Zn、Mn、Pb、Cd和Sb含量也高。相关性分析表明,污染程度与当地有色金属开采密切相关,主要污染物来源相同。一些痕量金属,如Zn、Cr、Cd,在土壤剖面中呈现先升高后降低的趋势。表层土壤出现了酸化现象。本研究明确了突发冶炼废水泄漏所造成的土壤金属污染特征,为污染治理提供了理论依据。

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