在光催化研究中，在二甲基甲酰胺中还原 CO2 时，水中甲酸定量的影响。
Effect of water during the quantitation of formate in photocatalytic studies on CO2 reduction in dimethylformamide.
机构信息
SRC for Solar Energy Conversion, School of Chemical Sciences, Dublin City University, Dublin 9, Ireland.
出版信息
Inorg Chem. 2012 Feb 20;51(4):1977-9. doi: 10.1021/ic202121s. Epub 2012 Feb 1.
PMID:22296290
Abstract
The effect of the water concentration on the quantitation of formate from dimethylformamide in the presence of electron-donating bases using ion chromatography is reported. This observation has important implications in the area of the photocatalytic reduction of CO(2), where formate levels are often used to calculate catalyst turnover numbers.
摘要
本文报道了在存在供电子碱基的情况下，水浓度对使用离子色谱法定量二甲基甲酰胺中甲酸盐的影响。这一观察结果在 CO(2)光催化还原领域具有重要意义，因为甲酸盐水平通常用于计算催化剂周转率。
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