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在流化床气化炉中气化稻草,用于在紧密耦合并联锅炉-气化炉系统中应用合成气。

Gasification of rice straw in a fluidized-bed gasifier for syngas application in close-coupled boiler-gasifier systems.

机构信息

Institute of Environment, Natural Resources and Biodiversity, University of León, Avda. Portugal, 41, 24071 León, Spain.

出版信息

Bioresour Technol. 2012 Apr;109:206-14. doi: 10.1016/j.biortech.2012.01.027. Epub 2012 Jan 14.

Abstract

The feasibility and operation performance of the gasification of rice straw in an atmospheric fluidized-bed gasifier was studied. The gasification was carried out between 700 and 850 °C. The stoichiometric air-fuel ratio (A/F) for rice straw was 4.28 and air supplied was 7-25% of that necessary for stoichiometric combustion. Mass and power balances, tar concentration, produced gas composition, gas phase ammonia, chloride and potassium concentrations, agglomeration tendencies and gas efficiencies were assessed. Agglomeration was avoided by replacing the normal alumina-silicate bed by a mixture of alumina-silicate sand and MgO. It was shown that it is possible to produce high quality syngas from the gasification of rice straw. Under the experimental conditions used, the higher heating value (HHV) of the produced gas reached 5.1 MJ Nm(-3), the hot gas efficiency 61% and the cold gas efficiency 52%. The obtained results prove that rice straw may be used as fuel for close-coupled boiler-gasifier systems.

摘要

研究了在常压流化床气化炉中气化稻草的可行性和运行性能。气化温度在 700 到 850°C 之间。稻草的化学计量空气燃料比(A/F)为 4.28,供气量为化学计量燃烧所需空气量的 7-25%。评估了质量和能量平衡、焦油浓度、产生的气体成分、气相氨、氯和钾浓度、团聚趋势和气体效率。通过用氧化铝-硅砂和 MgO 的混合物代替普通的氧化铝-硅酸盐床,避免了团聚。结果表明,从稻草的气化中可以生产出高质量的合成气。在所使用的实验条件下,产生的气体的高热值(HHV)达到 5.1 MJ Nm(-3),热气体效率为 61%,冷气体效率为 52%。所得结果证明,稻草可用作紧密耦合锅炉-气化炉系统的燃料。

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