Mercatelli Luca, Sani Elisa, Giannini Annalisa, Di Ninni Paola, Martelli Fabrizio, Zaccanti Giovanni
National Research Council-National Institute of Optics (CNR-INO), Largo E, Fermi, 6, Florence, 50125, Italy.
Nanoscale Res Lett. 2012 Feb 1;7(1):96. doi: 10.1186/1556-276X-7-96.
The full characterization of the optical properties of nanofluids consisting of single-wall carbon nanohorns of different morphologies in aqueous suspensions is carried out using a novel spectrophotometric technique. Information on the nanofluid scattering and absorption spectral characteristics is obtained by analyzing the data within the single scattering theory and validating the method by comparison with previous monochromatic measurements performed with a different technique. The high absorption coefficient measured joint to the very low scattering albedo opens promising application perspectives for single-wall carbon nanohorn-based fluid or solid suspensions. The proposed approximate approach can be extended also to other low-scattering turbid media.PACS: 78.35.+c Brillouin and Rayleigh scattering, other light scattering; 78.40.Ri absorption and reflection spectra, fullerenes and related materials; 81.05.U- carbon/carbon-based materials; 78.67.Bf optical properties of low-dimensional, mesoscopic, and nanoscale materials and structures, nanocrystals, nanoparticles, and nanoclusters.
采用一种新颖的分光光度技术,对由不同形态的单壁碳纳米角在水悬浮液中组成的纳米流体的光学性质进行了全面表征。通过在单次散射理论范围内分析数据,并与先前使用不同技术进行的单色测量结果进行比较来验证该方法,从而获得了纳米流体散射和吸收光谱特性的信息。测得的高吸收系数与极低的散射反照率相结合,为基于单壁碳纳米角的流体或固体悬浮液开辟了广阔的应用前景。所提出的近似方法也可以扩展到其他低散射浑浊介质。物理和天文学分类号:78.35.+c布里渊和瑞利散射,其他光散射;78.40.Ri吸收和反射光谱,富勒烯及相关材料;81.05.U-碳/碳基材料;78.67.Bf低维、介观和纳米级材料及结构、纳米晶体、纳米颗粒和纳米团簇的光学性质。