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载碲化镉纳米颗粒的活性炭作为吸附剂去除日落黄。

Cadmium telluride nanoparticles loaded on activated carbon as adsorbent for removal of sunset yellow.

机构信息

Chemistry Department, Yasouj University, Yasouj, Iran.

出版信息

Spectrochim Acta A Mol Biomol Spectrosc. 2012 May;90:22-7. doi: 10.1016/j.saa.2011.12.064. Epub 2011 Dec 30.

Abstract

Adsorption is a promising technique for decolorization of effluents of textile dyeing industries but its application is limited due to requirement of high amounts of adsorbent required. The objective of this study was to assess the potential of cadmium telluride nanoparticles loaded onto activated carbon (CdTN-AC) for the removal of sunset yellow (SY) dye from aqueous solution. Adsorption studies were conducted in a batch mode varying solution pH, contact time, initial dye concentration, CdTN-AC dose, and temperature. In order to investigate the efficiency of SY adsorption on CdTN-AC, pseudo-first-order, pseudo-second-order, Elovich, and intra-particle diffusion kinetic models were studied. It was observed that the pseudo-second-order kinetic model fits better than other kinetic models with good correlation coefficient. Equilibrium data were fitted to the Langmuir model. Thermodynamic parameters such as enthalpy, entropy, activation energy, and sticking probability were also calculated. It was found that the sorption of SY onto CdTN-AC was spontaneous and endothermic in nature. The proposed adsorbent is applicable for SY removal from waste of real effluents including pea-shooter, orange drink and jelly banana with efficiency more than 97%.

摘要

吸附是一种很有前途的技术,可用于对纺织印染工业废水进行脱色,但由于需要大量的吸附剂,因此其应用受到限制。本研究的目的是评估负载在活性炭上的碲化镉纳米粒子(CdTN-AC)对水溶液中日落黄(SY)染料的去除潜力。在批处理模式下进行吸附研究,改变溶液 pH、接触时间、初始染料浓度、CdTN-AC 剂量和温度。为了研究 SY 在 CdTN-AC 上吸附的效率,研究了拟一级、拟二级、Elovich 和内扩散动力学模型。结果表明,拟二级动力学模型比其他动力学模型更符合,具有良好的相关系数。平衡数据拟合到 Langmuir 模型。还计算了热力学参数,如焓、熵、活化能和粘着概率。结果表明,SY 在 CdTN-AC 上的吸附是自发的和吸热的。所提出的吸附剂适用于从豌豆射手、橙汁饮料和香蕉果冻等实际废水废物中去除 SY,去除效率超过 97%。

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