Akintayo Damilola Caleb, Yusuf Tunde Lewis, Mabuba Nonhlangabezo
Department of Chemical Sciences, Faculty of Science, University of Johannesburg, Doornfontein Campus, Johannesburg, 2028, South Africa.
Department of Chemistry, Faculty of Natural and Agricultural Sciences, University of Pretoria, Private Bag X20, Hatfield, Pretoria, 0028, South Africa.
Small. 2025 Jul;21(29):e2501378. doi: 10.1002/smll.202501378. Epub 2025 May 28.
Chalcogenide-based materials, known for their unique physicochemical properties, emerge as promising solutions for the removal of hazardous organic pollutants, such as dyes, pharmaceuticals, pesticides, and herbicides, from water and wastewater. This review examines the latest developments in the synthesis, structural optimization, and application of chalcogenide materials for environmental remediation. The past decade has witnessed remarkable advances in controlling the composition and structure of chalcogenide materials at the atomic level. The development of precise synthetic methods enables the creation of complex hierarchical structures, heterojunctions, and hybrid materials, leading to significant improvements in photocatalytic efficiency, stability, and selectivity for various environmental applications. Key emphasis is placed on adsorption and photocatalysis as green technologies, offering efficient pathways for pollutant removal. Mechanistic insights into the interactions between chalcogenide materials and contaminants are explored, providing a comprehensive understanding of their performance. Furthermore, challenges such as toxicity, scalability, and operational stability are discussed alongside future prospects for integrating these materials into industrial-scale water treatment systems. This review aims to inspire continued innovation in sustainable water purification technologies using chalcogenides.
硫族化物基材料因其独特的物理化学性质而闻名,成为从水和废水中去除有害有机污染物(如染料、药物、农药和除草剂)的有前景的解决方案。本文综述了硫族化物材料在环境修复方面的合成、结构优化及应用的最新进展。在过去十年中,在原子水平上控制硫族化物材料的组成和结构方面取得了显著进展。精确合成方法的发展使得能够创建复杂的分级结构、异质结和混合材料,从而在各种环境应用中显著提高光催化效率、稳定性和选择性。重点强调吸附和光催化作为绿色技术,为污染物去除提供了有效途径。探讨了硫族化物材料与污染物之间相互作用的机理,全面了解了它们的性能。此外,还讨论了毒性、可扩展性和操作稳定性等挑战以及将这些材料集成到工业规模水处理系统中的未来前景。本综述旨在激发利用硫族化物在可持续水净化技术方面的持续创新。