Université Joseph Fourier Grenoble 1/CNRS, Département de Chimie Moléculaire, UMR-5250, Institut de Chimie Moléculaire de Grenoble FR- CNRS-2607, Grenoble, France.
Dalton Trans. 2012 Mar 21;41(11):3130-3. doi: 10.1039/c2dt12355j. Epub 2012 Feb 8.
We have structurally and spectroscopically investigated a rare example of a mononuclear aliphatic dithiolate Cu(II) complex characterized by a reversible Cu(II)/Cu(I) redox couple. By DFT, we have shown that this system has a lower reorganization energy than its previously described bis(μ-thiolato) dicopper parent complex, which reversibly cycles between the Cu(1.5)Cu(1.5) and Cu(I)Cu(I) redox states.
我们对一个罕见的单核脂肪族二硫代 Cu(II) 配合物进行了结构和光谱研究，该配合物具有可逆的 Cu(II)/Cu(I) 氧化还原对。通过 DFT，我们表明该体系的重组能低于其先前描述的双(μ-硫代)二铜母体配合物，后者在 Cu(1.5)Cu(1.5)和 Cu(I)Cu(I)氧化还原态之间可逆循环。
