Department of Materials Science, Graduate School of Engineering, Tohoku University, Sendai, Japan.
Acta Biomater. 2012 May;8(5):1990-7. doi: 10.1016/j.actbio.2012.02.004. Epub 2012 Feb 9.
To develop a novel biomedical titanium alloy with a changeable Young's modulus via deformation-induced ω phase transformation for the spinal rods in spinal fixation devices, a series of metastable β type binary Ti-(15-18)Mo alloys were prepared. In this study, the microstructures, Young's moduli and tensile properties of the alloys were systemically examined to investigate the effects of deformation-induced ω phase transformation on their mechanical properties. The springback of the optimal alloy was also examined. Ti-(15-18)Mo alloys subjected to solution treatment comprise a β phase and a small amount of athermal ω phase, and they have low Young's moduli. All the alloys investigated in this study show an increase in the Young's modulus owing to deformation-induced ω phase transformation during cold rolling. The deformation-induced ω phase transformation is accompanied with {332}(β) mechanical twinning. This resulted in the maintenance of acceptable ductility with relatively high strength. Among the examined alloys, the Ti-17Mo alloy shows the lowest Young's modulus and the largest increase in the Young's modulus. This alloy exhibits small springback and could be easily bent to the required shape during operation. Thus, Ti-17Mo alloy is considered to be a potential candidate for the spinal rods in spinal fixation devices.
为了开发一种具有可变化学弹性模量的新型生物医学钛合金,通过变形诱导ω相转变用于脊柱固定装置中的脊柱棒,我们制备了一系列亚稳β型二元 Ti-(15-18)Mo 合金。在这项研究中,系统地研究了合金的微观结构、弹性模量和拉伸性能,以研究变形诱导ω相转变对其机械性能的影响。还研究了最佳合金的回弹性能。经过固溶处理的 Ti-(15-18)Mo 合金由β相和少量非热 ω 相组成,具有较低的弹性模量。本研究中研究的所有合金在冷轧过程中由于变形诱导的ω相转变而导致弹性模量增加。变形诱导的ω相转变伴随着{332}(β)机械孪晶。这使得在保持可接受的延展性的同时具有较高的强度。在所研究的合金中,Ti-17Mo 合金表现出最低的弹性模量和最大的弹性模量增加。该合金的回弹小,在操作过程中可以很容易地弯曲成所需的形状。因此,Ti-17Mo 合金被认为是脊柱固定装置中脊柱棒的潜在候选材料。