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Reversible formal insertion of CO2 into a remote C-H bond of a ligand in a Ru(II) complex at room temperature.在室温下，二价钌配合物中配体的远程 C-H 键可逆地插入 CO2。

Chem Commun (Camb). 2012 Jun 4;48(44):5416-8. doi: 10.1039/c2cc17933d. Epub 2012 Feb 13.

2

Tuning the reactivity of an actor ligand for tandem CO2 and C-H activations: from spectator metals to metal-free.调变双 CO2 和 C-H 活化的反应性：从旁观金属到无金属。

J Am Chem Soc. 2013 Oct 30;135(43):16175-83. doi: 10.1021/ja4073832. Epub 2013 Oct 17.

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Octahedral Ru(II) amido complexes TpRu(L)(L')(NHR) (Tp = hydridotris(pyrazolyl)borate; L = L' = P(OMe)3 or PMe3 or L = CO and L' = PPh3; R = H, Ph, or tBu): synthesis, characterization, and reactions with weakly acidic C-H bonds.八面体钌（II）酰胺配合物TpRu（L）（L'）（NHR）（Tp = 氢三（吡唑基）硼酸酯；L = L' = 三甲基磷酸酯或三甲基膦或L = CO且L' = 三苯基膦；R = H、苯基或叔丁基）：合成、表征以及与弱酸性C-H键的反应

Inorg Chem. 2003 Jul 28;42(15):4759-72. doi: 10.1021/ic034410a.

4

Bis(acetylacetonato)ruthenium(II) complexes containing alkynyldiphenylphosphines. Formation and redox behaviour of [Ru(acac)2(Ph2PC triple bond CR)2] (R=H, Me, Ph) complexes and the binuclear complex cis-[{Ru(acac)2}2(micro-Ph2PC triple bond CPPh2)}2].含炔基二苯基膦的双（乙酰丙酮）钌（II）配合物。[Ru(acac)2(Ph2PC≡CR)2]（R = H、Me、Ph）配合物及双核配合物顺式-[{Ru(acac)2}2(μ-Ph2PC≡CPPh2)}2]的形成与氧化还原行为

Dalton Trans. 2007 May 7(17):1677-86. doi: 10.1039/b618365d. Epub 2007 Mar 19.

5

An unusual dinuclear ruthenium(III) complex with a conjugated bridging ligand derived from cleavage of a 1,4-dihydro-1,2,4,5-tetrazine ring. Synthesis, structure, and UV-vis-NIR spectroelectrochemical characterization of a five-membered redox chain incorporating two mixed-valence states.一种不寻常的双核钌(III)配合物，其具有源自1,4-二氢-1,2,4,5-四嗪环裂解的共轭桥连配体。包含两种混合价态的五元氧化还原链的合成、结构及紫外-可见-近红外光谱电化学表征。

Inorg Chem. 2003 Jul 28;42(15):4707-13. doi: 10.1021/ic034131n.

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Reductive dimerization of triruthenium clusters containing cationic aromatic N-heterocyclic ligands.含正离子芳香族 N-杂环配体的三钌簇合物的还原二聚作用。

Chemistry. 2010 May 10;16(18):5425-36. doi: 10.1002/chem.200903313.

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Insertion reactions of hydridonitrosyltetrakis(trimethylphosphine) tungsten(0).氢亚硝酰四（三甲基膦）钨（0）的插入反应

Dalton Trans. 2005 Feb 7(3):580-7. doi: 10.1039/b414943b. Epub 2005 Jan 5.

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Structure and reactivity of bis(silyl) dihydride complexes (PMe(3))(3)Ru(SiR(3))(2)(H)(2): model compounds and real intermediates in a dehydrogenative C-Si bond forming reaction.双（硅基）二氢配合物(PMe(3))(3)Ru(SiR(3))(2)(H)(2)的结构与反应活性：脱氢C-Si键形成反应中的模型化合物与实际中间体

J Am Chem Soc. 2003 Jul 23;125(29):8936-48. doi: 10.1021/ja035916v.

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First example of mu(3)-sulfido bridged mixed-valent triruthenium complex triangle Ru(III)(2)Ru(II)(O,O-acetylacetonate)(3)(mu-O,O,gamma-C-acetylacetonate)(3)(mu(3)-S) (1) incorporating simultaneous O,O- and gamma-C-bonded bridging acetylacetonate units. Synthesis, crystal structure, and spectral and redox properties.首例含同时通过O,O-和γ-C键桥连乙酰丙酮单元的μ(3)-硫桥连混合价态三钌配合物三角Ru(III)₂Ru(II)(O,O-乙酰丙酮)(3)(μ-O,O,γ-C-乙酰丙酮)(3)(μ(3)-S) (1)。合成、晶体结构以及光谱和氧化还原性质。

Inorg Chem. 2003 Feb 24;42(4):1322-7. doi: 10.1021/ic026221i.

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Room-temperature regioselective C-H/olefin coupling of aromatic ketones using an activated ruthenium catalyst with a carbonyl ligand and structural elucidation of key intermediates.室温条件下，使用含羰基配体的钌催化剂实现芳香酮的区域选择性 C-H/烯烃偶联反应，并对关键中间体进行结构解析。

J Am Chem Soc. 2010 Dec 22;132(50):17741-50. doi: 10.1021/ja104918f. Epub 2010 Nov 29.

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在室温下，二价钌配合物中配体的远程 C-H 键可逆地插入 CO2。

Reversible formal insertion of CO2 into a remote C-H bond of a ligand in a Ru(II) complex at room temperature.

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