Food Engineering Department, Central Food Technological Research Institute, (Council of Scientific and Industrial Research), Mysore 570020, India.
Crit Rev Food Sci Nutr. 2012;52(4):334-46. doi: 10.1080/10408398.2010.500234.
Food gels are viscoelastic substances and several gelled products are manufactured throughout the world. The gelling agents in foods are usually polysaccharides and proteins. In food gels, the polymer molecules are not cross-linked by covalent bonds with the exception of disulphide bonds in some protein gels. Instead, the molecules are held together by a combination of weak inter-molecular forces like hydrogen bonds, electrostatic forces, Van der Waals forces, and hydrophobic interactions. Polysaccharides including hydrocolloids are strongly hydrated in aqueous medium but they tend to have less ordered structures. The mechanism of gelation depends on the nature of the gelling agent(s) and on the conditions of gel formation like the temperature, the presence of ions, the pH, and the concentration of gelling agents, etc. Characterization of gels can be performed in several ways of which rheological measurements are frequently practiced. Multi-component or mixed gel system is an important area of interest in which two or more gelling components are simultaneously used to achieve certain specific structural and functional characteristics. We here discuss about the different gels and gelling agents, the characterization of gels, and the mechanism of gelation with an emphasis on mixed or multi-component gels that would have significant commercial applications.
食品凝胶是黏弹性物质,全世界都在生产多种凝胶产品。食品中的胶凝剂通常是多糖和蛋白质。在食品凝胶中,除了某些蛋白质凝胶中的二硫键外,聚合物分子不通过共价键交联。相反,分子通过氢键、静电力、范德华力和疏水相互作用等弱分子间力结合在一起。多糖(包括水胶体)在水介质中强烈水合,但它们往往具有较少的有序结构。胶凝机制取决于胶凝剂的性质和胶凝形成的条件,如温度、离子存在、pH 值和胶凝剂浓度等。凝胶的表征可以通过多种方式进行,其中流变学测量是常用的方法之一。多组分或混合凝胶体系是一个重要的研究领域,其中同时使用两种或多种胶凝成分来实现某些特定的结构和功能特性。在这里,我们讨论了不同的凝胶和胶凝剂、凝胶的表征以及胶凝机制,重点介绍了具有重要商业应用前景的混合或多组分凝胶。