Inorganic Chemistry II, University of Bayreuth, Universitätsstr. 30, 95440 Bayreuth, Germany.
Chem Soc Rev. 2012 Aug 7;41(15):5102-16. doi: 10.1039/c2cs15326b. Epub 2012 Feb 15.
This tutorial review highlights the methods for the preparation of metal modified precursor derived ceramics (PDCs) and concentrates on the rare non-oxide systems enhanced with late transition metals. In addition to the main synthetic strategies for modified SiC and SiCN ceramics, an overview of the morphologies, structures and compositions of both, ceramic materials and metal (nano) particles, is presented. Potential magnetic and catalytic applications have been discussed for the so manufactured metal containing non-oxide ceramics.
本教程综述重点介绍了制备金属改性先驱体转化陶瓷(PDCs)的方法,并集中讨论了用晚期过渡金属增强的稀有非氧化物体系。除了改性 SiC 和 SiCN 陶瓷的主要合成策略外,还介绍了陶瓷材料和金属(纳米)颗粒的形貌、结构和组成的概述。讨论了制造的含金属非氧化物陶瓷的潜在磁性和催化应用。