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链状聚[[二水合-(2,2'-联吡啶-κN,N')锌]-μ-2,2'-[1,4-亚苯基-双(硫代二亚基)]二乙酸根-κO:O']

catena-Poly[[diaqua-(2,2'-bipyridine-κN,N')zinc]-μ-2,2'-[1,4-phenylene-bis(sulfanedi-yl)]diacetato-κO:O'].

作者信息

Lin Hong, Wang Xiao-Juan

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):m105. doi: 10.1107/S1600536811055310. Epub 2012 Jan 7.

Abstract

In the polymeric title complex, Zn(C(10)H(8)O(4)S(2))(C(10)H(8)N(2))(H(2)O)(2), the Zn(2+) ion lies on a twofold rotation axis and exhibits an octa-hedral environment, in which it is coordinated by two trans O atoms from two symmetry-related 2,2'-[1,4-phenyl-enebis(sulfanedi-yl)]diacetate anions, two N atoms from one 2,2'-bipyridine ligand, and two cis O atoms from water mol-ecules. The dihedral angle between the two pyridine rings is 11.5 (1)°. Adjacent Zn(2+) ions are bridged in a monodentate manner by the diacetate anions, forming a chain structure extending parallel to [101], and are further linked into the final three-dimensional structure by O-H⋯O hydrogen bonds between the coordinating water mol-ecules as donor and the non-coordinating carboxyl-ate O atoms as acceptor atoms.

摘要

在聚合标题配合物[Zn(C₁₀H₈O₄S₂)(C₁₀H₈N₂)(H₂O)₂]ₙ中,Zn²⁺离子位于二重旋转轴上,呈现八面体环境,其中它由来自两个对称相关的2,2'-[1,4-亚苯基双(硫代二亚基)]二乙酸根阴离子的两个反式O原子、来自一个2,2'-联吡啶配体的两个N原子以及来自水分子的两个顺式O原子配位。两个吡啶环之间的二面角为11.5 (1)°。相邻的Zn²⁺离子通过二乙酸根阴离子以单齿方式桥连,形成平行于[101]延伸的链状结构,并通过配位水分子作为供体与非配位羧酸根O原子作为受体原子之间的O—H⋯O氢键进一步连接成最终的三维结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/26cd/3274851/032bed93c161/e-68-0m105-fig1.jpg

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