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链状聚[[[四水合钴（II）]-μ-4,4'-联吡啶-κN:N'] 2-[4-（2-羧基-乙基）苯氧基]乙酸酯]

catena-Poly[[[tetra-aqua-cobalt(II)]-μ-4,4'-bipyridine-κN:N'] 2-[4-(2-carboxyl-ato-eth-yl)phen-oxy]acetate].

作者信息

Wang Xi-Fang, Liu Chong-Bo, Huang De-He, Xiong Zhi-Qiang

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 13;65(Pt 7):m764-5. doi: 10.1107/S1600536809021552.

DOI:10.1107/S1600536809021552
PMID:21582697
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2969250/
Abstract

In the title complex, {Co(C(10)H(8)N(2))(H(2)O)(4)}(n), the unique Co(II) ion lies on an inversion center and is coordinated by two N atoms from two 4,4'-bipyridine ligands and four O atoms from four water mol-ecules in a slightly distorted octa-hedral coordination geometry. The 4,4'-bipyridine ligands bridge Co(II) ions into a one-dimensional chain structure. In the crystal structure, inter-molecular O-H⋯O hydrogen bonds link cations and anions into a three-dimensional network. The dianions are completely disordered about an inversion center.

摘要

在标题配合物{Co(C₁₀H₈N₂)(H₂O)₄}ₙ中，独特的Co(II)离子位于一个对称中心上，由来自两个4,4'-联吡啶配体的两个N原子和来自四个水分子的四个O原子配位，形成略微扭曲的八面体配位几何构型。4,4'-联吡啶配体将Co(II)离子桥连形成一维链状结构。在晶体结构中，分子间的O-H⋯O氢键将阳离子和阴离子连接成三维网络。二价阴离子围绕一个对称中心完全无序。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/40ca/2969250/1a89a9436e49/e-65-0m764-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/40ca/2969250/1a89a9436e49/e-65-0m764-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/40ca/2969250/1a89a9436e49/e-65-0m764-fig1.jpg

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本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
2
Flexible sorption and transformation behavior in a microporous metal-organic framework.
J Am Chem Soc. 2002 Aug 14;124(32):9574-81. doi: 10.1021/ja0262737.