Suppr超能文献

链状聚[[[四水合钴(II)]-μ-4,4'-联吡啶-κN:N'] 2-[4-(2-羧基-乙基)苯氧基]乙酸酯]

catena-Poly[[[tetra-aqua-cobalt(II)]-μ-4,4'-bipyridine-κN:N'] 2-[4-(2-carboxyl-ato-eth-yl)phen-oxy]acetate].

作者信息

Wang Xi-Fang, Liu Chong-Bo, Huang De-He, Xiong Zhi-Qiang

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 13;65(Pt 7):m764-5. doi: 10.1107/S1600536809021552.

Abstract

In the title complex, {Co(C(10)H(8)N(2))(H(2)O)(4)}(n), the unique Co(II) ion lies on an inversion center and is coordinated by two N atoms from two 4,4'-bipyridine ligands and four O atoms from four water mol-ecules in a slightly distorted octa-hedral coordination geometry. The 4,4'-bipyridine ligands bridge Co(II) ions into a one-dimensional chain structure. In the crystal structure, inter-molecular O-H⋯O hydrogen bonds link cations and anions into a three-dimensional network. The dianions are completely disordered about an inversion center.

摘要

在标题配合物{Co(C₁₀H₈N₂)(H₂O)₄}ₙ中,独特的Co(II)离子位于一个对称中心上,由来自两个4,4'-联吡啶配体的两个N原子和来自四个水分子的四个O原子配位,形成略微扭曲的八面体配位几何构型。4,4'-联吡啶配体将Co(II)离子桥连形成一维链状结构。在晶体结构中,分子间的O-H⋯O氢键将阳离子和阴离子连接成三维网络。二价阴离子围绕一个对称中心完全无序。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/40ca/2969250/1a89a9436e49/e-65-0m764-fig1.jpg

文献AI研究员

20分钟写一篇综述,助力文献阅读效率提升50倍。

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

文档翻译

学术文献翻译模型,支持多种主流文档格式。

立即体验