Wang Xi-Fang, Liu Chong-Bo, Huang De-He, Xiong Zhi-Qiang
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 13;65(Pt 7):m764-5. doi: 10.1107/S1600536809021552.
In the title complex, {Co(C(10)H(8)N(2))(H(2)O)(4)}(n), the unique Co(II) ion lies on an inversion center and is coordinated by two N atoms from two 4,4'-bipyridine ligands and four O atoms from four water mol-ecules in a slightly distorted octa-hedral coordination geometry. The 4,4'-bipyridine ligands bridge Co(II) ions into a one-dimensional chain structure. In the crystal structure, inter-molecular O-H⋯O hydrogen bonds link cations and anions into a three-dimensional network. The dianions are completely disordered about an inversion center.
在标题配合物{Co(C₁₀H₈N₂)(H₂O)₄}ₙ中,独特的Co(II)离子位于一个对称中心上,由来自两个4,4'-联吡啶配体的两个N原子和来自四个水分子的四个O原子配位,形成略微扭曲的八面体配位几何构型。4,4'-联吡啶配体将Co(II)离子桥连形成一维链状结构。在晶体结构中,分子间的O-H⋯O氢键将阳离子和阴离子连接成三维网络。二价阴离子围绕一个对称中心完全无序。