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二-μ-氯-双-{双-[4-(金刚烷-1-基氨甲酰基)吡啶-κN]氯合铜(II)}半水合物

Di-μ-chlorido-bis-{bis-[4-(adamantan-1-ylcarbamo-yl)pyridine-κN]chlorido-copper(II)} hemihydrate.

作者信息

Wang Ying-Chun

机构信息

College of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):m147. doi: 10.1107/S1600536812000670. Epub 2012 Jan 14.

DOI:10.1107/S1600536812000670
PMID:22346828
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3274881/
Abstract

In the centrosymmetric dimeric title compound, [Cu(2)Cl(4)(C(16)H(20)N(2)O)(4)]·0.5H(2)O, the Cu(II) atom is in a distorted trigonal-bipyramidal environment defined by two bridging Cl atoms, one terminal Cl atom and two N atoms from two monodentate 4-(adamantan-1-ylcarbamo-yl)pyridine ligands. The amine N atoms are involved in intra-molecular N-H⋯O and inter-molecular N-H⋯Cl hydrogen bonds. The latter hydrogen bonds link the complex mol-ecules into a ribbon along [010]. The uncoordinated water mol-ecule is 0.25-occupied.

摘要

在中心对称的二聚体标题化合物[Cu₂Cl₄(C₁₆H₂₀N₂O)₄]·0.5H₂O中，Cu(II)原子处于由两个桥连Cl原子、一个端基Cl原子以及来自两个单齿4-(金刚烷-1-基氨基甲酰基)吡啶配体的两个N原子所定义的扭曲三角双锥环境中。胺N原子参与分子内N-H⋯O和分子间N-H⋯Cl氢键的形成。后者的氢键将配合物分子沿[010]方向连接成一条链。未配位的水分子占有率为0.25。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ce34/3274881/3160adb1a63b/e-68-0m147-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ce34/3274881/901ee56c6c2b/e-68-0m147-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ce34/3274881/3160adb1a63b/e-68-0m147-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ce34/3274881/901ee56c6c2b/e-68-0m147-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ce34/3274881/3160adb1a63b/e-68-0m147-fig2.jpg

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