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二-μ-氯-双-{水合氯[2,2'-硫代双(吡啶 N-氧化物)-κO]铜(II)}

Di-μ-chlorido-bis-{aqua-chlorido[2,2'-thio-bis(pyridine N-oxide)-κO]copper(II)}.

作者信息

Seidel Rüdiger W, Oppel Iris M

机构信息

Analytische Chemie, Ruhr-Universität Bochum, Universitätsstrasse 150, 44780 Bochum, Germany.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 28;65(Pt 4):m460. doi: 10.1107/S1600536809011076.

DOI:10.1107/S1600536809011076
PMID:21582393
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2968806/
Abstract

The crystal structure of the title compound, [Cu(2)Cl(4)(C(10)H(8)N(2)O(2)S)(2)(H(2)O)(2)], comprises neutral centrosymmetric μ-chloride-bridged dinuclear units. Each Cu(II) ion is penta-coordinated by three chloride ligands, a pyridine N-oxide O atom and a water mol-ecule. Intra- and inter-molecular O-H⋯O hydrogen bonds occur between the coordinated water mol-ecules and the uncoordinated and coordinated pyridine N-oxide groups of the 2,2'-thio-bis(pyridine N-oxide) ligands, respectively.

摘要

标题化合物[Cu₂Cl₄(C₁₀H₈N₂O₂S)₂(H₂O)₂]的晶体结构由中心对称的μ-氯桥连双核单元组成。每个Cu(II)离子由三个氯配体、一个吡啶N-氧化物O原子和一个水分子进行五配位。配位水分子分别与2,2'-硫代双(吡啶N-氧化物)配体的未配位和配位吡啶N-氧化物基团之间存在分子内和分子间的O-H⋯O氢键。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fe7/2968806/26f913df956b/e-65-0m460-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fe7/2968806/fa7a2c796fee/e-65-0m460-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fe7/2968806/26f913df956b/e-65-0m460-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fe7/2968806/fa7a2c796fee/e-65-0m460-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3fe7/2968806/26f913df956b/e-65-0m460-fig2.jpg

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