[3-甲氧基-1-(苯硫基)丙基]三苯基锡(IV)苯0.17溶剂化物
[3-Meth-oxy-1-(phenyl-sulfan-yl)prop-yl]triphenyl-tin(IV) benzene 0.17-solvate.
作者信息
Ludwig Gerd, Block Michael, Wagner Christoph, Steinborn Dirk
机构信息
Institut für Chemie - Anorganische Chemie, Martin-Luther-Universität Halle-Wittenberg, D-06120 Halle, Kurt-Mothes-Strasse 2, Germany.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):m149. doi: 10.1107/S1600536811055474. Epub 2012 Jan 14.
In the title compound, [Sn(C(6)H(5))(3)(C(10)H(13)OS)]·0.17C(6)H(6), the Sn(IV) atom exhibits a slightly distorted tetra-hedral coordination geometry built up by four C atoms, which are the three ipso-C atoms of the phenyl rings and the α-C atom of the deprotonated γ-O-functionalized propyl phenyl sulfide. The benzene mol-ecule lies about a threefold rotoinversion axis.
在标题化合物[Sn(C₆H₅)₃(C₁₀H₁₃OS)]·0.17C₆H₆中，Sn(IV)原子呈现出由四个C原子构成的略微扭曲的四面体配位几何构型，这四个C原子分别是苯环的三个本位C原子以及去质子化的γ-O-官能化丙基苯硫醚的α-C原子。苯分子位于一个三重旋转反演轴上。
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