三环己基{2-[(3,5-二叔丁基-4-羟基苄基)硫烷基]乙酸根合-κO}锡(IV)
Tricyclo-hex-yl{2-[(3,5-di-tert-butyl-4-hy-droxy-benz-yl)sulfan-yl]acetato-κO}tin(IV).
作者信息
Lee See Mun, Mohd Ali Hapipah, Lo Kong Mun
机构信息
Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 16;66(Pt 7):m792. doi: 10.1107/S1600536810021884.
Abstract
The title compound, [Sn(C(6)H(11))(3)(C(17)H(25)O(3)S)], exists as a monomeric mol-ecule with the Sn(IV) atom in a distorted tetra-hedral C(3)O coordination geometry. The presence of two bulky tert-butyl groups on the carboxyl-ate prevents any hydrogen-bonding inter-actions involving the hy-droxy group.
摘要
标题化合物[Sn(C₆H₁₁)₃(C₁₇H₂₅O₃S)]以单体分子形式存在，其中Sn(IV)原子处于扭曲的四面体C₃O配位几何构型中。羧酸酯上两个庞大的叔丁基的存在阻止了任何涉及羟基的氢键相互作用。
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