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三环己基{2-[(3,5-二叔丁基-4-羟基苄基)硫烷基]乙酸根合-κO}锡(IV)

Tricyclo-hex-yl{2-[(3,5-di-tert-butyl-4-hy-droxy-benz-yl)sulfan-yl]acetato-κO}tin(IV).

作者信息

Lee See Mun, Mohd Ali Hapipah, Lo Kong Mun

机构信息

Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 16;66(Pt 7):m792. doi: 10.1107/S1600536810021884.

DOI:10.1107/S1600536810021884
PMID:21587716
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3007050/
Abstract

The title compound, [Sn(C(6)H(11))(3)(C(17)H(25)O(3)S)], exists as a monomeric mol-ecule with the Sn(IV) atom in a distorted tetra-hedral C(3)O coordination geometry. The presence of two bulky tert-butyl groups on the carboxyl-ate prevents any hydrogen-bonding inter-actions involving the hy-droxy group.

摘要

标题化合物[Sn(C₆H₁₁)₃(C₁₇H₂₅O₃S)]以单体分子形式存在，其中Sn(IV)原子处于扭曲的四面体C₃O配位几何构型中。羧酸酯上两个庞大的叔丁基的存在阻止了任何涉及羟基的氢键相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f156/3007050/a6cb358a1fb9/e-66-0m792-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f156/3007050/a6cb358a1fb9/e-66-0m792-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f156/3007050/a6cb358a1fb9/e-66-0m792-fig1.jpg

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本文引用的文献

1
Tricyclo-hexyl(2,3-dibromo-3-phenyl-propionato-κO)tin(IV).三环己基（2,3 - 二溴 - 3 - 苯基丙酸根 - κO）锡（IV）
Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 8;65(Pt 5):m490. doi: 10.1107/S1600536809012240.
2
catena-Poly[[triphenyl-tin(IV)]-μ-2-[(3,5-di-tert-butyl-4-hydroxy-benz-yl)sulfan-yl]acetato-κO:O'].链状聚[[三苯基锡(IV)]-μ-2-[(3,5-二叔丁基-4-羟基苄基)硫烷基]乙酸根-κO:O']
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 20;65(Pt 7):m808. doi: 10.1107/S1600536809023150.
3
2-[(3,5-Di-tert-butyl-4-hydroxy-benz-yl)-sulfan-yl]-N'-isopropyl-ideneaceto-hydrazide.
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Acta Crystallogr Sect E Struct Rep Online. 2010 Feb 17;66(Pt 3):m307. doi: 10.1107/S1600536810005830.
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