钯催化的苄位 C-H 键芳基化/氧化反应。

Pd-catalyzed arylation/oxidation of benzylic C-H bond.

机构信息

Department of Chemistry, Zhejiang University, Hangzhou 310027, People's Republic of China.

出版信息

Org Lett. 2012 Mar 2;14(5):1238-41. doi: 10.1021/ol300037p. Epub 2012 Feb 22.

Abstract

A palladium-catalyzed benzylic C-H arylation/oxidation reaction leading to diaryl ketones has been accomplished. The indispensable role of the bidentate system is disclosed for this sequential process. This chemistry offers a direct new access to a range of diarylketones.

摘要

钯催化的苄位 C-H 芳基化/氧化反应生成二芳基酮已经完成。双齿体系在这个顺序过程中起着不可或缺的作用。这种化学为一系列二芳基酮提供了直接的新途径。