State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, P. R. China.
Chem Commun (Camb). 2012 Jul 11;48(54):6782-4. doi: 10.1039/c2cc18111h. Epub 2012 Feb 24.
Twin growth in the synthesis of b-oriented MFI films is successfully suppressed by applying microwave irradiation on a b-oriented MFI seed layer, relying on the nucleation-related bottleneck effect. Electrochemical oxidation experiments demonstrated the importance of twin suppression in enhancing the diffusion of guest molecules in MFI films.
微波辐照法成功抑制了 b 取向 MFI 种子层上 b 取向 MFI 膜的孪晶生长，这是基于成核相关的瓶颈效应。电化学氧化实验证明了抑制孪晶对于提高客体分子在 MFI 膜中扩散的重要性。
