Institute of General and Ecological Chemistry, Technical University of Łódź, Poland.
Angew Chem Int Ed Engl. 2012 Mar 12;51(11):2564-601. doi: 10.1002/anie.201105125. Epub 2012 Feb 28.
In view of the diminishing oil resources and the ongoing climate change, the use of efficient and environmentally benign technologies for the utilization of renewable resources has become indispensible. Therein, hydrogenolysis reactions offer a promising possibility for future biorefinery concepts. These reactions result in the cleavage of C-C and C-O bonds by hydrogen and allow direct access to valuable platform chemicals already integrated in today's value chains. Thus, hydrogenolysis bears the potential to bridge currently available technologies and future biomass-based refinery concepts. This Review highlights past and present developments in this field, with special emphasis on the direct utilization of cellulosic feedstocks.
鉴于石油资源的减少和持续的气候变化，利用高效且环境友好的技术来利用可再生资源已变得不可或缺。在这些技术中，氢解反应为未来的生物炼制概念提供了有前景的可能性。这些反应通过氢使 C-C 和 C-O 键断裂，并允许直接获得已经集成在当今价值链中的有价值的平台化学品。因此，氢解有可能连接当前可用的技术和未来基于生物质的炼油厂概念。本文综述了该领域过去和现在的发展情况，特别强调了对纤维素原料的直接利用。
