State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, PR China.
Angew Chem Int Ed Engl. 2012 Apr 2;51(14):3432-5. doi: 10.1002/anie.201108220. Epub 2012 Feb 28.
A color change: X-ray-induced photochromic species are rare and can be used for detection of X-rays. A highly robust X-ray-sensitive material with the discrete structure of a metal-organic complex has been found to show both soft and hard X-ray-induced photochromism at room temperature. A new ligand-to-ligand electron-transfer mechanism was proposed to elucidate this photochromic phenomenon.
X 射线诱导的光致变色物种很少见，可用于检测 X 射线。一种具有金属-有机配合物离散结构的高稳定性的 X 射线敏感材料，在室温下表现出软 X 射线和硬 X 射线诱导的光致变色。提出了一种新的配体-配体电子转移机制来阐明这种光致变色现象。
