Key Laboratory of Synthetic Chemistry of Natural Substances, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China.
Chem Commun (Camb). 2012 Apr 11;48(29):3530-2. doi: 10.1039/c2cc17882f. Epub 2012 Mar 1.
Sequential biomimetic elaborations, featured by CrO(3)-mediated oxidative lactonization, and DDQ-involved oxidative enol-lactonization, ensured the concise total synthesis of (+)-chloranthalactone F.
连续的仿生衍生化反应,其特征为 CrO(3)介导的氧化内酯化和 DDQ 参与的氧化烯醇内酯化,确保了(+)-chloranthalactone F 的简洁全合成。