由手性恶唑硼烷催化的乙烯酮与醛的对映选择性β-内酯形成反应。
Enantioselective beta-lactone formation from ketene and aldehydes catalyzed by a chiral oxazaborolidine.
作者信息
Gnanadesikan Vijay, Corey E J
机构信息
Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, USA.
出版信息
Org Lett. 2006 Oct 12;8(21):4943-5. doi: 10.1021/ol061979h.
PMID:17020342
Abstract
[reaction: see text] A novel catalytic system has been developed for the enantioselective synthesis of beta-lactones from ketene and aldehydes.
摘要
[反应：见正文] 已开发出一种新型催化体系，用于从乙烯酮和醛对映选择性合成β-内酯。
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