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通过原位透射电子显微镜揭示锂化-脱锂过程中 CuO 纳米线的转化机制。

Revealing the conversion mechanism of CuO nanowires during lithiation-delithiation by in situ transmission electron microscopy.

机构信息

International Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), Namiki 1-1, Tsukuba, Ibaraki, 305-0044, Japan.

出版信息

Chem Commun (Camb). 2012 May 18;48(40):4812-4. doi: 10.1039/c2cc30643c. Epub 2012 Mar 5.

Abstract

Being promising candidates for anodes in lithium-ion batteries (LIBs), transition metal oxide anodes utilizing the so-called conversion mechanism principle typically suffer from the severe capacity fading during the 1st cycle of lithiation-delithiation. Herein, we directly investigated these processes using an individual CuO nanowire anode and constructed a lithium ion battery (LIB) prototype within a transmission electron microscope.

摘要

作为锂离子电池(LIBs)阳极的有前途的候选者,利用所谓的转换机制原理的过渡金属氧化物阳极通常在锂化-脱锂的第一个循环中遭受严重的容量衰减。在此,我们使用单个 CuO 纳米线阳极直接研究这些过程,并在透射电子显微镜内构建了一个锂离子电池(LIB)原型。

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