James Franck Institute, University of Chicago, 929 East 57th Street, Chicago, IL 60637, USA.
Proc Natl Acad Sci U S A. 2012 Mar 20;109(12):4389-94. doi: 10.1073/pnas.1111060109. Epub 2012 Mar 5.
When a dense suspension is squeezed from a nozzle, droplet detachment can occur similar to that of pure liquids. While in pure liquids the process of droplet detachment is well characterized through self-similar profiles and known scaling laws, we show here the simple presence of particles causes suspensions to break up in a new fashion. Using high-speed imaging, we find that detachment of a suspension drop is described by a power law; specifically we find the neck minimum radius, r(m), scales like near breakup at time τ = 0. We demonstrate data collapse in a variety of particle/liquid combinations, packing fractions, solvent viscosities, and initial conditions. We argue that this scaling is a consequence of particles deforming the neck surface, thereby creating a pressure that is balanced by inertia, and show how it emerges from topological constraints that relate particle configurations with macroscopic Gaussian curvature. This new type of scaling, uniquely enforced by geometry and regulated by the particles, displays memory of its initial conditions, fails to be self-similar, and has implications for the pressure given at generic suspension interfaces.
当浓稠悬浮液从喷嘴中挤出时,液滴可能会脱离,这与纯液体的情况类似。在纯液体中,液滴脱离的过程具有相似的自相似形态和已知的标度律,但我们在此展示了一个简单的事实,即颗粒的存在会使悬浮液以一种新的方式破裂。通过高速成像,我们发现悬浮液滴的脱离可以用幂律来描述;具体来说,我们发现颈部最小半径 r(m) 在时间 τ = 0 时接近断裂,呈标度律关系。我们在各种颗粒/液体组合、堆积分数、溶剂粘度和初始条件下展示了数据的崩溃。我们认为这种标度律是颗粒使颈部表面变形的结果,从而产生了与惯性平衡的压力,并展示了它是如何从与宏观高斯曲率相关的颗粒配置的拓扑约束中出现的。这种由几何形状唯一强制且由颗粒调节的新型标度律,表现出对初始条件的记忆,不能自相似,并对一般悬浮液界面处的压力产生影响。