Department of Biochemical Engineering, Graduate School of Science and Engineering, Yamagata University, 4-3-16 Jonan, Yonezawa 992-8510, Japan.
J Org Chem. 2012 Apr 6;77(7):3595-7. doi: 10.1021/jo202630p. Epub 2012 Mar 19.
An enantioresolution of 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl oxide (BINAPO) into its enantiomers was achieved using the inclusion complex with a commerciallyavailable chiral 2,2'-dihydroxy-1,1'-binaphthyl ((R)-BINOL), giving the two enantiomers with 99% ee and 72% ee, respectively.
手性 2,2'-二羟基-1,1'-联萘 ((R)-BINOL) 的包合物实现了 2,2'-双(二苯基膦基)-1,1'-联萘氧化物 (BINAPO) 的对映体拆分，分别得到对映体过量值为 99%和 72%的两种对映体。
