School of Chemistry, The University of Dublin, Trinity College, Dublin 2, Ireland.
Chem Commun (Camb). 2012 Apr 18;48(31):3742-4. doi: 10.1039/c2cc18022g. Epub 2012 Mar 8.
The synthesis of photoluminescent conjugated polymer silica ionogels using sol-gel chemistry is described. Cooperative self-assembly of an ionic liquid, the silica precursor and poly(9,9-dioctylfluorene) (PFO) via hydrogen bonding and π-stacking interactions drives formation of the PFO β-phase.
采用溶胶-凝胶化学方法合成了光致发光共轭聚合物硅氧烷离子凝胶。通过氢键和π-堆积相互作用，离子液体、硅前驱体和聚（9,9-二辛基芴）（PFO）协同自组装驱动 PFOβ相的形成。
