糠醛醇与甲基(1-溴-2,3,4-三-O-乙酰-α-D-吡喃葡萄糖醛酸酯)的 Koenigs-Knorr 反应生成保护的烷基葡萄糖醛酸苷-晶体结构和高分辨率 1H 和 13C NMR 数据。
Koenigs-Knorr reaction of fusel alcohols with methyl (1-bromo-2,3,4-tri-O-acetyl-α-D-glucopyranosid)uronate leading to the protected alkyl glucuronides-crystal structures and high resolution 1H and 13C NMR data.
机构信息
BAM Federal Institute for Materials Research and Testing, Berlin, Germany.
出版信息
Carbohydr Res. 2012 May 1;352:186-90. doi: 10.1016/j.carres.2012.01.002. Epub 2012 Jan 13.
PMID:22402102
Abstract
Crystal structures and high resolution (1)H and (13)C NMR spectral data for methyl (alkyl 2,3,4-tri-O-acetyl-β-D-glucopyranosid)uronates (alkyl=methyl, ethyl, n-propyl, i-propyl, n-butyl, sec-butyl, i-butyl, n-pentyl, 2-methyl-1-butyl and 3-methyl-1-butyl) are presented.
摘要
呈现了甲基（烷基 2,3,4-三-O-乙酰基-β-D-吡喃葡萄糖苷基）尿苷酸酯（烷基=甲基、乙基、正丙基、异丙基、正丁基、仲丁基、异丁基、正戊基、2-甲基-1-丁基和 3-甲基-1-丁基）的晶体结构和高分辨率 (1)H 和 (13)C NMR 光谱数据。
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