具有[6]螺旋桨骨架的 1,8-萘酰亚胺的合成与表征。
Synthesis and characterization of 1,8-naphthalimide with [6]helicene skeleton.
机构信息
Graduate School of Pharmaceutical Sciences, Kyushu University, 3-1-1 Maidashi, Fukuoka, 812-8582, Japan.
出版信息
Org Biomol Chem. 2012 Apr 21;10(15):2934-6. doi: 10.1039/c2ob25223f. Epub 2012 Mar 12.
PMID:22407552
Abstract
A 1,8-naphthalimide with [6]helicene derivative scaffold has been designed and synthesized. The (P)- and (M)-enantiomers of the [6]helicene derivative were resolved by HPLC on a chiral column. The single crystal of the [6]helicene derivative exhibits an intermolecular interactions of the 1,8-naphthalimide units.
摘要
设计并合成了一种具有[6]螺烯衍生物支架的 1,8-萘酰亚胺。通过手性柱上的 HPLC 对[6]螺烯衍生物的(P)-和(M)-对映异构体进行拆分。[6]螺烯衍生物的单晶表现出 1,8-萘酰亚胺单元的分子间相互作用。
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