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链状聚[[(1,10-菲咯啉-κN,N')铅(II)]-二-μ-硝酸根-κO,O':O'';κO:O',O''-[(1,10-菲咯啉-κN,N')铅(II)]-双-(μ-2,2,2-三氯乙酸根-κO:O')]

catena-Poly[[(1,10-phenanthroline-κN,N')lead(II)]-di-μ-nitrato-κO,O':O'';κO:O',O''-[(1,10-phenanthroline-κN,N')lead(II)]-bis-(μ-2,2,2-trichloro-acetato-κO:O')].

作者信息

Shahverdizadeh Gholam Hossein, Ng Seik Weng, Tiekink Edward R T, Mirtamizdoust Babak

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Mar 1;68(Pt 3):m237-8. doi: 10.1107/S1600536812003595. Epub 2012 Feb 4.

DOI:10.1107/S1600536812003595
PMID:22412401
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3297211/
Abstract

In the title Pb(II) complex, Pb(2)(C(2)Cl(3)O(2))(2)(NO(3))(2)(C(12)H(8)N(2))(2), the 1,10-phenanthroline ligand is chelating, the nitrate anion chelates one Pb(II) ion and simultaneously bridges a neighbouring Pb(II) ion via the third O atom, and the trichloro-acetate anion is bidentate, bridging two Pb(II) ions. The coordination geometry is based on a penta-gonal-bipramidal geometry defined by an N(2)O(5) donor set with no obvious stereochemical role for the lead-bound lone pair of electrons. The coordination polymer has a zigzag topology along [010] and comprises alternating eight-membered {PbONO}(2) and {PbOCO}(2) rings.

摘要

在标题为Pb(2)(C(2)Cl(3)O(2))(2)(NO(3))(2)(C(12)H(8)N(2))(2)的Pb(II)配合物中，1,10 - 菲咯啉配体为螯合配体，硝酸根阴离子螯合一个Pb(II)离子，同时通过第三个O原子桥连相邻的Pb(II)离子，三氯乙酸根阴离子为双齿配体，桥连两个Pb(II)离子。配位几何构型基于由N(2)O(5)供体集定义的五角双锥几何构型，铅结合的孤对电子没有明显的立体化学作用。该配位聚合物沿[010]具有锯齿状拓扑结构，由交替的八元{PbONO}(2)和{PbOCO}(2)环组成。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7b1f/3297211/e0df45d669e0/e-68-0m237-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7b1f/3297211/7db668f4993f/e-68-0m237-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7b1f/3297211/eb18c6d77147/e-68-0m237-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7b1f/3297211/e0df45d669e0/e-68-0m237-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7b1f/3297211/7db668f4993f/e-68-0m237-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7b1f/3297211/eb18c6d77147/e-68-0m237-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7b1f/3297211/e0df45d669e0/e-68-0m237-fig3.jpg

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本文引用的文献

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Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1729-30. doi: 10.1107/S1600536811046769. Epub 2011 Nov 9.
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catena-Poly[[lead(II)-μ-N'-[1-(pyridin-2-yl-κN)ethyl-idene]isonicotino-hydrazidato-κN',O:N] perchlorate].链状聚[[铅（II）-μ-N'-[1-（吡啶-2-基-κN）亚乙基]异烟酸酰肼基-κN'，O:N]高氯酸盐]
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1727-8. doi: 10.1107/S1600536811046691. Epub 2011 Nov 9.
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A short history of SHELX.
SHELX简史。
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