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二氯化μ(3)-氯代-三-(双-{1-[2-(二甲基氨基)乙基]-3-甲基咪唑-2-亚基}银(I))

μ(3)-Chlorido-tris-(bis-{1-[2-(dimethyl-amino)-eth-yl]-3-methyl-imidazol-2-yl-idene}silver(I)) dichloride.

作者信息

Topf Christoph, Leitner Sebastian, Monkowius Uwe

机构信息

Johannes Kepler Universität Linz, Institut für Anorganische Chemie, Altenbergerstrasse 69, A-4040 Linz, Austria.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Mar 1;68(Pt 3):m272. doi: 10.1107/S1600536812004473. Epub 2012 Feb 10.

DOI:10.1107/S1600536812004473
PMID:22412422
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3297232/
Abstract

In the crystal structure of the title compound, [Ag(3)Cl(C(8)H(15)N(3))(6)]Cl(2), the Ag(I) ion, which is located on a twofold rotation axis, exists in a T-shape coordination environment. Two carbene C atoms of the N-heterocyclic carbene (NHC) ligands are bonded tightly forming a slightly bent Ag(NHC)(2) cation [C-Ag-C angle = 162.80 (18)°]. Three of these complex cations are further aggregated by one bridging chloride anion, which is lying on a threefold rotoinversion axis and is only loosely binding to the Ag(+) ions. The N atom of the amine group is not engaged in any coordinative bond.

摘要

在标题化合物[Ag₃Cl(C₈H₁₅N₃)₆]Cl₂的晶体结构中，位于二重旋转轴上的Ag(I)离子存在于T形配位环境中。N-杂环卡宾（NHC）配体的两个卡宾C原子紧密键合，形成一个略微弯曲的[Ag(NHC)₂]⁺阳离子[C-Ag-C角 = 162.80 (18)°]。三个这样的络合阳离子通过一个桥连氯离子进一步聚集，该氯离子位于三重旋转反演轴上，仅与Ag⁺离子松散结合。胺基的N原子不参与任何配位键。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/807d/3297232/bdce9d029626/e-68-0m272-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/807d/3297232/5d3e7bfd3253/e-68-0m272-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/807d/3297232/bdce9d029626/e-68-0m272-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/807d/3297232/5d3e7bfd3253/e-68-0m272-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/807d/3297232/bdce9d029626/e-68-0m272-fig2.jpg

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