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氯化双{[1-苄基-3-(2,4,6-三甲基苯基)咪唑-2-亚基-κ]银(I)}·1,2-二氯乙烷半溶剂合物

μ-Chlorido-bis-{[1-benzyl-3-(2,4,6-tri-methyl-phen-yl)imidazol-2-yl-idene-κ]silver(I)} chloride 1,2-di-chloro-ethane hemisolvate.

作者信息

Malek Kotiba, Arumugam Kuppuswamy

机构信息

Department of Chemistry, Wright State University, 3640 Colonel Glenn Hwy, Dayton, OH 45435, USA.

出版信息

IUCrdata. 2024 Sep 10;9(Pt 9):x240861. doi: 10.1107/S2414314624008617. eCollection 2024 Sep.

DOI:10.1107/S2414314624008617
PMID:39371668
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11451033/
Abstract

The title compound, [Ag(CHN)]Cl·0.5CHCl, can be readily generated by treatment of (1-benzyl-3-(2,4,6-tri-methyl-phen-yl)imidazolium chloride with sodium bis-(tri-methyl-sil-yl)amide followed by silver chloride. The mol-ecular structure of the compound was confirmed using NMR spectroscopy and single-crystal X-ray diffraction analysis. The crystal structure of the title compound at 110 K has monoclinic (2/) symmetry. The represented silver compound is of inter-est with respect to anti-bacterial properties and the structure displays a series of weak inter-molecular hydrogen-bonding inter-actions with the chloride counter-anion.

摘要

标题化合物[Ag(CHN)]Cl·0.5CHCl可通过用双（三甲基硅基）酰胺钠处理（1-苄基-3-（2,4,6-三甲基苯基）咪唑鎓氯化物，随后加入氯化银轻松制得。该化合物的分子结构通过核磁共振光谱和单晶X射线衍射分析得以确认。标题化合物在110 K时的晶体结构具有单斜（2/）对称性。所呈现的银化合物在抗菌性能方面具有研究价值，且该结构与氯化物抗衡阴离子展现出一系列微弱的分子间氢键相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ae05/11451033/ae678cd766b4/x-09-x240861-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ae05/11451033/5b1a7a2bc7fb/x-09-x240861-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ae05/11451033/df6de944099b/x-09-x240861-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ae05/11451033/bbe95c0fbecb/x-09-x240861-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ae05/11451033/ae678cd766b4/x-09-x240861-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ae05/11451033/5b1a7a2bc7fb/x-09-x240861-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ae05/11451033/df6de944099b/x-09-x240861-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ae05/11451033/bbe95c0fbecb/x-09-x240861-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ae05/11451033/ae678cd766b4/x-09-x240861-fig4.jpg

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