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使用功能化 PBG 折射率传感器对溶剂蒸气中的萘进行高灵敏度检测。

Highly sensitive detection of naphthalene in solvent vapor using a functionalized PBG refractive index sensor.

机构信息

University of Applied Sciences Aschaffenburg, Würzburger Strasse 45, D-63743 Aschaffenburg, Germany.

出版信息

Sensors (Basel). 2012;12(2):2018-25. doi: 10.3390/s120202018. Epub 2012 Feb 13.

DOI:10.3390/s120202018
PMID:22438751
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3304153/
Abstract

We report an optical refractive index sensor system based on a planar Bragg grating which is functionalized by substituted γ-cyclodextrin to determine low concentrations of naphthalene in solvent vapor. The sensor system exhibits a quasi-instantaneous shift of the Bragg wavelength and is therefore capable for online detection. The overall shift of the Bragg wavelength reveals a linear relationship to the analyte concentration with a gradient of 12.5 ± 1.5 pm/ppm. Due to the spectral resolution and repeatability of the interrogation system, this corresponds to acquisition steps of 80 ppb. Taking into account the experimentally detected signal noise a minimum detection limit of 0.48 ± 0.05 ppm is deduced.

摘要

我们报告了一种基于平面布拉格光栅的光折射指数传感器系统,该系统通过取代的 γ-环糊精功能化,用于测定溶剂蒸气中萘的低浓度。该传感器系统表现出布拉格波长的准瞬时移动,因此能够进行在线检测。布拉格波长的整体移动与分析物浓度呈线性关系,斜率为 12.5 ± 1.5 pm/ppm。由于询问系统的光谱分辨率和可重复性,这对应于 80 ppb 的采集步骤。考虑到实验检测到的信号噪声,推断出的最小检测限为 0.48 ± 0.05 ppm。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bb70/3304153/d5e6460edea9/sensors-12-02018f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bb70/3304153/cb1e80df4dc9/sensors-12-02018f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bb70/3304153/2fb6e964c063/sensors-12-02018f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bb70/3304153/7d5d8ee2e2d2/sensors-12-02018f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bb70/3304153/d5e6460edea9/sensors-12-02018f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bb70/3304153/cb1e80df4dc9/sensors-12-02018f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bb70/3304153/2fb6e964c063/sensors-12-02018f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bb70/3304153/7d5d8ee2e2d2/sensors-12-02018f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/bb70/3304153/d5e6460edea9/sensors-12-02018f4.jpg

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