Institute of Chemical Technology, Department of Analytical Chemistry, Technická 5, Praha 6, 166 28, Czech Republic.
Chem Soc Rev. 2012 May 21;41(10):3839-58. doi: 10.1039/c2cs15307f. Epub 2012 Mar 22.
Oligo Tröger's bases are compounds containing two or more Tröger's base subunits (1,5-methanodiareno[b,f][1,5]diazocines) sharing one or more arene parts. Due to their interesting molecular shapes, these compounds are studied as chiral molecular tweezers, clips, cavitands, clefts, calixes, etc. This review includes all available data on oligo Tröger's bases, and introduces their preparation and properties to a wide audience.
寡聚 Troger 碱是指含有两个或多个 Troger 碱亚基(1,5-亚甲基二萘并[b,f][1,5]二氮杂环辛烯)共享一个或多个芳烃部分的化合物。由于它们具有有趣的分子形状,这些化合物被研究为手性分子夹、夹子、主体、裂缝、杯芳烃等。本综述包括关于寡聚 Troger 碱的所有现有数据,并向广大读者介绍它们的制备和性质。