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垃圾生物覆盖土壤中垃圾稳定化过程中 H2S 去除的机理:一种替代的垃圾覆盖。

Mechanism of H2S removal during landfill stabilization in waste biocover soil, an alterative landfill cover.

机构信息

Department of Environmental Engineering, Zhejiang University, Hangzhou 310058, China.

出版信息

J Hazard Mater. 2012 May 30;217-218:67-75. doi: 10.1016/j.jhazmat.2012.02.061. Epub 2012 Mar 3.

Abstract

Hydrogen sulfide (H(2)S) is one of the primary contributors to odors at landfills. The mechanism of waste biocover soil (WBS) for H(2)S removal was investigated in simulated landfill systems with the contrast experiment of a landfill cover soil (LCS). The H(2)S removal efficiency was higher than 90% regardless of the WBS or LCS covers. The input of landfill gas (LFG) could stimulate the growth of aerobic heterotrophic bacteria, actinomycete, sulfate-reducing bacteria (SRB) and sulfur-oxidizing bacteria (SOB) in the WBS cover, while that caused a decrease of 1-2 orders of magnitude in the populations of actinomycete and fungi in the bottom layer of the LCS cover. As H(2)S inputted, the sulfide content in the WBS cover increased and reached the maximum on day 30. In the LCS cover, the highest soil sulfide content was exhibited in the bottom layer during the whole experiment. After exposure to LFG, the lower pH value and higher sulfate content were observed in the top layer of the WBS cover, while there was not a significant difference in different layers of the LCS cover. The results indicated a more rapid biotransformation between sulfide and sulfate occurred in the WBS cover compared to the LCS.

摘要

硫化氢(H2S)是垃圾填埋场臭味的主要来源之一。本研究采用模拟垃圾填埋场系统,通过垃圾覆盖土(LCS)的对比实验,研究了垃圾生物覆盖土(WBS)去除 H2S 的机理。无论采用 WBS 还是 LCS 覆盖,H2S 的去除效率均高于 90%。填埋气(LFG)的输入可以刺激 WBS 覆盖层中好氧异养细菌、放线菌、硫酸盐还原菌(SRB)和硫氧化菌(SOB)的生长,而 LCS 覆盖层底部的放线菌和真菌数量减少了 1-2 个数量级。随着 H2S 的输入,WBS 覆盖层中的硫化物含量增加,并在第 30 天达到最大值。在 LCS 覆盖层中,整个实验过程中底部的土壤硫化物含量最高。暴露于 LFG 后,WBS 覆盖层的顶层呈现出较低的 pH 值和较高的硫酸盐含量,而 LCS 覆盖层的不同层之间没有显著差异。结果表明,与 LCS 相比,WBS 覆盖层中硫化物和硫酸盐之间的生物转化更为迅速。

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