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垃圾填埋场内源性 H2S 的缓解。

Endogenous mitigation of H2S inside of the landfills.

机构信息

Zhejiang Provincial Key Laboratory of Solid Waste Treatment and Recycling, School of Environmental Science and Engineering, Zhejiang Gongshang University, Hangzhou, 310012, China.

Zhejiang Environmental Science and Design Institute, Hangzhou, 310007, China.

出版信息

Environ Sci Pollut Res Int. 2016 Feb;23(3):2505-12. doi: 10.1007/s11356-015-5482-7. Epub 2015 Oct 1.

Abstract

Vast quantities of hydrogen sulfide (H2S) emitted from landfill sites require urgent disposal. The current study focused on source control and examined the migration and conversion behavior of sulfur compounds in two lab-scale simulated landfills with different operation modes. It aimed to explore the possible strategies and mechanisms for H2S endogenous mitigation inside of landfills during decomposition. It was found that the strength of H2S emissions from the landfill sites was dependent on the municipal solid waste (MSW) degradation speed and vertical distribution of sulfide. Leachate recirculation can shorten both the H2S influence period and pollution risk to the surrounding environment. H2S endogenous mitigation may be achieved by chemical oxidation, biological oxidation, adsorption, and/or precipitation in different stages. Migration and conversion mainly affected H2S release behavior during the initial stabilization phase in the landfill. Microbial activities related to sulfur, nitrogen, and iron can further promote H2S endogenous mitigation during the high reducing phase. Thus, H2S endogenous mitigation can be effectively enhanced via control of the aforementioned processes.

摘要

大量的硫化氢(H2S)从垃圾填埋场排放,需要紧急处理。本研究侧重于源头控制,并在两个具有不同操作模式的实验室规模模拟垃圾填埋场中考察了硫化合物的迁移和转化行为。目的是探讨在垃圾填埋场内分解过程中 H2S 内源性缓解的可能策略和机制。研究发现,垃圾填埋场 H2S 排放的强度取决于城市固体废物(MSW)降解速度和硫化物的垂直分布。渗滤液再循环可以缩短 H2S 的影响期和对周围环境的污染风险。在不同阶段,H2S 内源性缓解可以通过化学氧化、生物氧化、吸附和/或沉淀来实现。迁移和转化主要影响垃圾填埋场初始稳定阶段的 H2S 释放行为。与硫、氮和铁有关的微生物活动可以在高还原阶段进一步促进 H2S 内源性缓解。因此,通过控制上述过程可以有效地增强 H2S 内源性缓解。

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