Department of Chemistry and RU INSTM, University of Florence, Italy.
Angew Chem Int Ed Engl. 2012 May 14;51(20):4792-800. doi: 10.1002/anie.201105428. Epub 2012 Apr 4.
The comparison of the structural and magnetic properties of molecular nanomagnets (MNM) and magnetic nanoparticles (MNP) can be instructive to get a deeper understanding of the magnetic behavior on the intermediate scale between molecular and bulk objects. In this respect iron oxo based clusters are particularly interesting, since they provide an increasing number of molecular systems with sizes close to that of iron oxide MNP. In this Minireview we report a survey of literature data aimed at improving our understanding of the emergence of MNP properties from MNM ones.
比较分子纳米磁体（MNM）和磁性纳米颗粒（MNP）的结构和磁性能，可以深入了解分子和块状物体之间的中间尺度的磁行为。在这方面，基于铁氧体的簇合物特别有趣，因为它们为具有接近氧化铁 MNP 尺寸的分子体系提供了越来越多的分子体系。在这篇综述中，我们报告了文献数据的调查，旨在提高我们对从 MNM 中出现 MNP 特性的理解。
