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A structural model for heme in high-spin ferric hemoproteins. Iron atom centering, porphinato core expansion, and molecular stereochemistry of high-spin diaquo(meso-tetraphenylporphinato)iron(III) perchlorate.

作者信息

Scheidt W R, Cohen I A, Kastner M E

出版信息

Biochemistry. 1979 Aug 7;18(16):3546-52. doi: 10.1021/bi00583a017.

DOI:10.1021/bi00583a017
PMID:224911
Abstract
摘要

相似文献

1
A structural model for heme in high-spin ferric hemoproteins. Iron atom centering, porphinato core expansion, and molecular stereochemistry of high-spin diaquo(meso-tetraphenylporphinato)iron(III) perchlorate.高自旋铁血红素蛋白中血红素的结构模型。高自旋二水合（内消旋 - 四苯基卟吩）高氯酸铁（III）的铁原子居中、卟吩核扩张及分子立体化学。
Biochemistry. 1979 Aug 7;18(16):3546-52. doi: 10.1021/bi00583a017.
2
Modulation of metal displacements in a saddle distorted macrocycle: synthesis, structure, and properties of high-spin Fe(III) porphyrins and implications for the hemoproteins.鞍形扭曲大环中金属位移的调控：高自旋Fe(III)卟啉的合成、结构与性质及其对血红蛋白的启示
Inorg Chem. 2008 Sep 15;47(18):8324-35. doi: 10.1021/ic800944q. Epub 2008 Aug 14.
3
Heme models. I. Solution behavior of a water soluble iron porphyrin.
Bioinorg Chem. 1976;5(3):219-33. doi: 10.1016/s0006-3061(00)82020-7.
4
Five-coordinate iron-porphyrin as a model for the active site of hemoproteins. Characterization and coordination properties.
Eur J Biochem. 1976 Dec;71(1):63-76. doi: 10.1111/j.1432-1033.1976.tb11090.x.
5
Iron 10-thiacorroles: bioinspired iron(III) complexes with an intermediate spin (S=3/2) ground state.铁-10-硫杂卟啉：具有中间自旋（S = 3/2）基态的仿生铁（III）配合物。
Chemistry. 2014 Mar 3;20(10):2913-24. doi: 10.1002/chem.201303786. Epub 2014 Jan 29.
6
Stereochemistry of hemes and other metalloporphyrins.血红素及其他金属卟啉的立体化学
Science. 1971 Dec 24;174(4016):1295-302. doi: 10.1126/science.174.4016.1295.
7
A possible model of hemoprotein-peroxide complexes formed in an iron-tetraphenylporphyrin system.
Biochem Biophys Res Commun. 1986 Mar 28;135(3):972-8. doi: 10.1016/0006-291x(86)91023-5.
8
Resonance Raman studies on the ligand-iron interactions in hemoproteins and metallo-porphyrins.关于血红蛋白和金属卟啉中配体-铁相互作用的共振拉曼光谱研究。
Adv Biophys. 1978;11:153-96.
9
Molecular stereochemistry of [FeIII(TPP)(OCOCF3)].
Acta Crystallogr C. 1995 Aug 15;51 ( Pt 8):1490-4. doi: 10.1107/s010827019401334x.
10
Recent developments in the investigation of the paramagnetic centers in low-spin ferric hemoproteins: carbon-13 hyperfine shifts in iron porphyrin complexes.
Ann N Y Acad Sci. 1973 Dec 31;222:709-21. doi: 10.1111/j.1749-6632.1973.tb15297.x.

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Differential coordination demands in Fe versus Mn water-soluble cationic metalloporphyrins translate into remarkably different aqueous redox chemistry and biology.铁卟啉与锰卟啉水溶性阳离子金属配合物的配位差异要求导致其在水相氧化还原化学和生物学方面表现出显著不同。
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