Department of Physical Sciences, The Open University, Walton Hall, Milton Keynes, MK7 6AA, United Kingdom.
J Chem Phys. 2012 Apr 14;136(14):144310. doi: 10.1063/1.3702629.
We present theoretical elastic and electronic excitation cross sections and experimental electronic excitation cross sections for electron collisions with pyrimidine. We use the R-matrix method to determine elastic integral and differential cross sections and integral inelastic cross sections for energies up to 15 eV. The experimental inelastic cross sections have been determined in the 15-50 eV impact energy range. Typically, there is quite reasonable agreement between the theoretical and experimental integral inelastic cross sections. Calculated elastic cross sections agree very well with prior results.
我们给出了嘧啶与电子碰撞的理论弹性和电子激发截面以及实验电子激发截面。我们使用 R 矩阵方法确定了能量高达 15 eV 的弹性积分和微分截面以及积分非弹性截面。实验非弹性截面已在 15-50 eV 碰撞能量范围内确定。通常,理论和实验积分非弹性截面之间有相当合理的一致性。计算的弹性截面与先前的结果非常吻合。