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生物过滤处理城市污水:各种处理布局的比较。第 1 部分:碳和氮的去除评估。

Municipal wastewater treatment by biofiltration: comparisons of various treatment layouts. Part 1: assessment of carbon and nitrogen removal.

机构信息

SIAAP - Direction du Développement et de la Prospective, 82 avenue Kléber, F-92700 Colombes, France.

出版信息

Water Sci Technol. 2012;65(9):1705-12. doi: 10.2166/wst.2012.105.

DOI:10.2166/wst.2012.105
PMID:22508136
Abstract

One of the largest wastewater treatment plants in the Paris conurbation (240,000 m(3)/d) has been studied over several years in order to provide technical and economical information about biological treatment by biofiltration. Biofiltration systems are processes in which carbon and nitrogen pollution of wastewater are treated by ascendant flow through immersed fixed cultures. This paper, focused on technical information, aims: (1) to compare performances of the three biological treatment layouts currently used in biofiltration systems: upstream denitrification (UD), downstream denitrification (DD) and combined upstream-downstream denitrification (U-DD) layouts; and (2) to describe in detail each treatment step. Our study has shown that more than 90% of the carbon and ammoniacal pollution is removed during biological treatment, whatever the layout used. Nitrate, produced during nitrification, is then reduced to atmospheric nitrogen. This reduction is more extensive when the denitrification stage occurs downstream from the treatment (DD layout with methanol addition), whereas it is only partial when it is inserted upstream from the treatment (UD layout - use of endogenous carbonaceous substrate). So, the UD layout leads to a nitrate concentration that exceeds the regulatory threshold in the effluent, and the treatment must be supplemented with a post-denitrification step (U-DD layout). Our work has also shown that the optimal ammonium-loading rate is about 1.1-1.2 kg N-NH(4)(+) per m(3) media (polystyrene) and day. For denitrification, the optimal nitrate-loading rate is about 2.5 kg N per m(3) media (expanded clay) and day in the case of DD with methanol, and is about 0.25 kg N-NO(3)(-) per m(3) media and day in the case of UD with exogenous carbonaceous substrate.

摘要

巴黎城市群最大的污水处理厂之一(240000 立方米/天)已经被研究了好几年,目的是为生物过滤的生物处理提供技术和经济信息。生物过滤系统是一种将污水中的碳和氮污染物通过上升流穿过浸入式固定培养物进行处理的工艺。本文主要关注技术信息,旨在:(1)比较目前生物过滤系统中三种生物处理布局的性能:上游反硝化(UD)、下游反硝化(DD)和联合上游-下游反硝化(U-DD)布局;(2)详细描述每个处理步骤。我们的研究表明,无论使用哪种布局,超过 90%的碳和氨污染在生物处理过程中被去除。在硝化过程中产生的硝酸盐随后被还原为大气氮。当反硝化阶段发生在处理之后(添加甲醇的 DD 布局)时,这种还原更为广泛,而当它插入处理之前时(使用内源性碳质基质的 UD 布局)则只是部分还原。因此,UD 布局导致出水中硝酸盐浓度超过法规阈值,必须进行后反硝化处理(U-DD 布局)。我们的工作还表明,最佳氨负荷率约为 1.1-1.2 kg N-NH(4)(+)每立方米介质(聚苯乙烯)和天。对于反硝化,在添加甲醇的 DD 情况下,最佳硝酸盐负荷率约为 2.5 kg N 每立方米介质(膨胀粘土)和天,而在使用外源性碳质基质的 UD 情况下,最佳硝酸盐负荷率约为 0.25 kg N-NO(3)(-)每立方米介质和天。

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