(-)-苦木灵的简洁全合成。
Concise total synthesis of (-)-mersicarpine.
机构信息
Graduate School of Pharmaceutical Sciences, Tohoku University, Aramaki, Aoba-ku, Sendai 980-8578, Japan.
出版信息
Org Lett. 2012 May 4;14(9):2320-2. doi: 10.1021/ol300735g. Epub 2012 Apr 18.
PMID:22512929
Abstract
A concise total synthesis of (-)-mersicarpine from a known cyclohexanone was accomplished. The azepinoindole core was constructed by a DIBAL-H-mediated reductive ring-expansion reaction of oxime.
摘要
从已知的环己酮出发，简洁地全合成了（-）-麦斯卡林。氮杂吲哚核心通过 DIBAL-H 介导的肟还原环扩反应构建。
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