Max-Planck-Institut für Festkörperforschung, Stuttgart, Germany.
J Phys Condens Matter. 2012 Jun 13;24(23):233201. doi: 10.1088/0953-8984/24/23/233201. Epub 2012 May 3.
In this review we consider three classes of superconductors, namely cuprate superconductors, MgB(2) and the new Fe based superconductors. All of these three systems are layered materials and multiband compounds. Their pairing mechanisms are under discussion with the exception of MgB(2), which is widely accepted to be a 'conventional' electron-phonon interaction mediated superconductor, but extending the Bardeen-Cooper-Schrieffer (BCS) theory to account for multiband effects. Cuprates and Fe based superconductors have higher superconducting transition temperatures and more complex structures. Superconductivity is doping dependent in these material classes unlike in MgB(2) which, as a pure compound, has the highest values of T(c) and a rapid suppression of superconductivity with doping takes place. In all three material classes isotope effects have been observed, including exotic ones in the cuprates, and controversial ones in the Fe based materials. Before the area of high-temperature superconductivity, isotope effects on T(c) were the signature for phonon mediated superconductivity-even when deviations from the BCS value to smaller values were observed. Since the discovery of high T(c) materials this is no longer evident since competing mechanisms might exist and other mediating pairing interactions are discussed which are of purely electronic origin. In this work we will compare the three different material classes and especially discuss the experimentally observed isotope effects of all three systems and present a rather general analysis of them. Furthermore, we will concentrate on multiband signatures which are not generally accepted in cuprates even though they are manifest in various experiments, the evidence for those in MgB(2), and indications for them in the Fe based compounds. Mostly we will consider experimental data, but when possible also discuss theoretical models which are suited to explain the data.
在这篇综述中,我们考虑了三类超导体,即铜酸盐超导体、MgB2 和新型 Fe 基超导体。这三种体系都是层状材料和多带化合物。除了 MgB2 之外,它们的配对机制都在讨论之中,MgB2 被广泛认为是一种“传统”的电子-声子相互作用介导的超导体,但它扩展了 Bardeen-Cooper-Schrieffer (BCS) 理论,以解释多带效应。铜酸盐和 Fe 基超导体具有更高的超导转变温度和更复杂的结构。与 MgB2 不同,在这些材料体系中,超导性是依赖掺杂的,而 MgB2 作为一种纯化合物,具有最高的 Tc 值,并且掺杂会迅速抑制超导性。在所有这三种材料体系中,都观察到了同位素效应,包括铜酸盐中的奇异同位素效应,以及 Fe 基材料中的有争议的同位素效应。在高温超导领域出现之前,Tc 上的同位素效应是声子介导超导的标志——即使观察到偏离 BCS 值到较小的值。自从发现高温超导材料以来,这种情况不再明显,因为可能存在竞争机制,并且还讨论了其他纯粹是电子起源的介导配对相互作用。在这项工作中,我们将比较这三种不同的材料体系,特别是讨论所有这三种体系的实验观察到的同位素效应,并对它们进行相当一般的分析。此外,我们将集中讨论多带特征,即使在各种实验中都表现出来,但在铜酸盐中还没有被普遍接受,尽管在 MgB2 中存在证据,在 Fe 基化合物中也有迹象。我们将主要考虑实验数据,但在可能的情况下,也将讨论适合解释数据的理论模型。