Hao Haijun, Zhu Baichun, Yi Jianjun
Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):m351-2. doi: 10.1107/S1600536812005880. Epub 2012 Mar 3.
The mol-ecular structure of the title compound, [Al(CH(3))(2)(C(22)H(26)NO)], displays a monomer with the Al(III) atom in a distorted tetra-hedral environment defined by two methyl groups and the N and O atoms of the chelating ketiminate anion. The O-Al-N bite angle of the chelating ligand is 94.14 (9)°. The O-C-C-C-N backbone of the ligand is nearly coplanar (r.m.s. deviation = 0.029 Å) and the Al atom deviates significantly from the mean plane by 0.525 (3) Å. In the crystal, weak inter-molecular C-H⋯O inter-actions are observed.
标题化合物[Al(CH(3))(2)(C(22)H(26)NO)]的分子结构显示为一个单体,其中Al(III)原子处于由两个甲基以及螯合酮亚胺阴离子的N和O原子所定义的扭曲四面体环境中。螯合配体的O-Al-N夹角为94.14 (9)°。配体的O-C-C-C-N主链近乎共面(均方根偏差 = 0.029 Å),且Al原子偏离平均平面达0.525 (3) Å。在晶体中,观察到微弱的分子间C-H⋯O相互作用。