• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

聚[μ(2)-水-双-[μ(4)-2-(1H-1,2,3-苯并三唑-1-基)乙酸根]]-二钾

Poly[μ(2)-aqua-bis-[μ(4)-2-(1H-1,2,3-benzotriazol-1-yl)acetato]-dipotassium].

作者信息

Liu Qiong

机构信息

Department of Environment Engineering and Chemistry, Luoyang Institute of Science and Technology, 471023 Luoyang, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):m379. doi: 10.1107/S1600536812008963. Epub 2012 Mar 7.

DOI:10.1107/S1600536812008963
PMID:22589770
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3343796/
Abstract

In the title compound, K(2)(C(8)H(6)N(3)O(2))(2)(H(2)O), each K(+) ion is seven-coordinated by one O atom from a bridging water mol-ecule, five carboxyl-ate O atoms and one N atom from a benzotriazole group, forming a distorted mono-capped octa-hedral geometry. In the crystal, the carboxyl-ate groups act as bridging ligands, forming a two-dimensional polymer parallel to (001). The aqua ligand, which lies on a twofold rotation axis, forms inter-molecular O-H⋯O hydrogen bonds within these layers.

摘要

在标题化合物[K₂(C₈H₆N₃O₂)₂(H₂O)]ₙ中，每个K⁺离子由一个桥连水分子中的一个O原子、五个羧酸根O原子和一个苯并三唑基团的一个N原子七配位，形成扭曲的单帽八面体几何构型。在晶体中，羧酸根基团作为桥连配体，形成平行于(001)的二维聚合物。位于二重旋转轴上的水配体在这些层内形成分子间O—H⋯O氢键。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3bc5/3343796/e7b0252a9e26/e-68-0m379-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3bc5/3343796/ca47d6aae44c/e-68-0m379-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3bc5/3343796/e7b0252a9e26/e-68-0m379-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3bc5/3343796/ca47d6aae44c/e-68-0m379-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3bc5/3343796/e7b0252a9e26/e-68-0m379-fig2.jpg

相似文献

1
Poly[μ(2)-aqua-bis-[μ(4)-2-(1H-1,2,3-benzotriazol-1-yl)acetato]-dipotassium].聚[μ(2)-水-双-[μ(4)-2-(1H-1,2,3-苯并三唑-1-基)乙酸根]]-二钾
Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):m379. doi: 10.1107/S1600536812008963. Epub 2012 Mar 7.
2
Poly[bis-(μ(4)-acetato-κO:O:O':O')bis-(μ(3)-acetato-κO:O:O)(μ(2)-acetato-κO:O')(μ(2)-acetic acid-κO:O')di-μ-aqua-copper(II)tris-odium].聚[双（μ(4)-乙酸根-κO:O:O':O'）双（μ(3)-乙酸根-κO:O:O）（μ(2)-乙酸根-κO:O'）（μ(2)-乙酸-κO:O'）双-μ-水合铜（II）三钠]
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 11;66(Pt 10):m1244. doi: 10.1107/S1600536810035683.
3
Poly[di-μ-aqua-diaqua-di-μ(6)-malonato-cobalt(II)dipotassium(I)].聚[二-μ-水-二水-二-μ(6)-丙二酸根合钴(II)二钾(I)]
Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):m601. doi: 10.1107/S1600536811012839. Epub 2011 Apr 16.
4
Poly[μ-aqua-diaquabis-[μ-2-cyano-2-(oxidoimino)-acetato]-copper(II)dipotassium].聚[μ-水-二水双-[μ-2-氰基-2-(氧化亚氨基)-乙酸根合]-铜(II)二钾]
Acta Crystallogr Sect E Struct Rep Online. 2012 Oct 1;68(Pt 10):m1303-4. doi: 10.1107/S1600536812036641. Epub 2012 Sep 26.
5
Poly[μ(2)-aqua-aqua-(μ(3)-1H-benzimidazole-5,6-dicarboxyl-ato-κN:O:O)manganese(II)].聚[μ(2)-水-水-(μ(3)-1H-苯并咪唑-5,6-二羧酸根合-κN:O:O)锰(II)]
Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 10;66(Pt 5):m511. doi: 10.1107/S1600536810011979.
6
Poly[[tetra-aqua-bis-(μ(3)-5-carboxybenzene-1,2,4-tri-carboxyl-ato)tricadmium] tetra-hydrate].聚[[四水合双(μ(3)-5-羧基苯-1,2,4-三羧酸根)三镉]四水合物]
Acta Crystallogr Sect E Struct Rep Online. 2012 Jun 1;68(Pt 6):m801-2. doi: 10.1107/S1600536812022726. Epub 2012 May 26.
7
catena-Poly[[[aqua-[(2-hydroxy-phen-yl)acetato-κO,O']lead(II)]-μ(3)-[(2-hydroxy-phen-yl)acetato-κO:O,O':O']] monohydrate].链状聚[[[水合-[(2-羟基苯基)乙酸根-κO,O']铅(II)]-μ(3)-[(2-羟基苯基)乙酸根-κO:O,O':O']]一水合物]
Acta Crystallogr Sect E Struct Rep Online. 2010 Feb 6;66(Pt 3):m273-4. doi: 10.1107/S1600536810004162.
8
Poly[[aqua-(μ(7)-biphenyl-3,3',4,4'-tetra-carboxyl-ato)(1,10-phenanthroline)dicobalt(II)] monohydrate].聚[[水合-(μ(7)-联苯-3,3',4,4'-四羧酸根)(1,10-菲咯啉)二钴(II)]一水合物]
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):m1118. doi: 10.1107/S1600536811028224. Epub 2011 Jul 23.
9
Poly[μ₂-aqua-μ₄-(2-{3-[(6-chloro-pyridin-3-yl)meth-yl]-2-oxoimidazolidin-1-yl}acetato)-sodium].聚[μ₂-水-μ₄-(2-{3-[(6-氯吡啶-3-基)甲基]-2-氧代咪唑烷-1-基}乙酸根合)-钠]
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):m891-2. doi: 10.1107/S1600536812025007. Epub 2012 Jun 13.
10
Bis[[aqua-(1H-imidazo[4,5-f][1,10]phenanthroline-κN,N)cadmium]bis-(μ-pyridine-2,3-dicarboxyl-ato)-κN,O:O;κO:N,O].双[[水合-(1H-咪唑并[4,5-f][1,10]菲咯啉-κN,N)镉]双-(μ-吡啶-2,3-二羧酸根)-κN,O:O;κO:N,O]
Acta Crystallogr Sect E Struct Rep Online. 2012 Mar 1;68(Pt 3):m301. doi: 10.1107/S160053681200579X. Epub 2012 Feb 17.

引用本文的文献

1
Crystal structure of -bis-[2-(1-benzotriazol-1-yl)acetato-κ]bis-(ethano-lamine-κ ,)copper(II).双[2-(1-苯并三唑-1-基)乙酸根-κ]双(乙醇胺-κN,)铜(II)的晶体结构
Acta Crystallogr E Crystallogr Commun. 2019 Jan 18;75(Pt 2):233-236. doi: 10.1107/S2056989019000744. eCollection 2019 Feb 1.

本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.