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聚[μ₂-水-μ₄-(2-{3-[(6-氯吡啶-3-基)甲基]-2-氧代咪唑烷-1-基}乙酸根合)-钠]

Poly[μ₂-aqua-μ₄-(2-{3-[(6-chloro-pyridin-3-yl)meth-yl]-2-oxoimidazolidin-1-yl}acetato)-sodium].

作者信息

Kant Rajni, Gupta Vivek K, Kapoor Kamini, Shripanavar Chetan S, Banerjee Kaushik, Deshmukh Madhukar B

机构信息

X-ray Crystallography Laboratory, Post-Graduate Department of Physics & Electronics, University of Jammu, Jammu Tawi 180 006, India.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):m891-2. doi: 10.1107/S1600536812025007. Epub 2012 Jun 13.

Abstract

In the title compound, Na(C₁₁H₁₁ClN₃O₃)(H₂O), there are two independent Na(I) ions, one of which lies on an inversion center and is coordinated in a slightly distorted octa-hedral environment. The other Na(I) ion lies on a twofold rotation axis and is cooordinated in a slightly distorted trigonal-bipyramidal coordination environment. In the organic ligand, the imidazolidine ring adopts a half-chair conformation. The Na(I) ions bridge organic ligands and water mol-ecules, forming a two-dimensional structure parallel to (100). There are inter-molecular O-H⋯O and weak C-H⋯O hydrogen bonds within the two-dimensional structure.

摘要

在标题化合物[Na(C₁₁H₁₁ClN₃O₃)(H₂O)]ₙ中,存在两个独立的Na(I)离子,其中一个位于对称中心,在略微扭曲的八面体环境中配位。另一个Na(I)离子位于二重旋转轴上,在略微扭曲的三角双锥配位环境中配位。在有机配体中,咪唑烷环呈半椅构象。Na(I)离子连接有机配体和水分子,形成平行于(100)的二维结构。在二维结构内存在分子间O-H⋯O和弱C-H⋯O氢键。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2e8c/3393166/e59eb6148634/e-68-0m891-fig1.jpg

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