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二羰基-{3,3'-二叔丁基-5,5'-二甲氧基-2,2'-双-[(4,4,5,5-四苯基-1,3,2-二氧磷杂环戊烷-2-基)-氧代-κP]联苯基}氢铑(I) 二乙醚单溶剂合物

Dicarbonyl-{3,3'-di-tert-butyl-5,5'-di-meth-oxy-2,2'-bis-[(4,4,5,5-tetra-phenyl-1,3,2-dioxa-phospho-lan-2-yl)-oxy-κP]biphen-yl}hydridorhodium(I) diethyl ether monosolvate.

作者信息

Selent Detlef, Spannenberg Anke, Börner Armin

机构信息

Leibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):m488. doi: 10.1107/S1600536812011786. Epub 2012 Mar 28.

DOI:10.1107/S1600536812011786
PMID:22589846
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3343872/
Abstract

In the title compound, [Rh(C(74)H(68)O(8)P(2))H(CO)(2)]·C(4)H(10)O, the C(2)HP(2) coordination set at the Rh(I) ion is arranged in a distorted trigonal-planar geometry with one P atom of the diphosphite mol-ecule and the H atom adopting the axial coordination sites.

摘要

在标题化合物[Rh(C₇₄H₆₈O₈P₂)H(CO)₂]·C₄H₁₀O中，Rh(I)离子处的C₂HP₂配位基团呈扭曲的三角平面几何构型，亚磷酸二酯分子的一个P原子和H原子占据轴向配位位点。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/05d3/3343872/4e649c252a71/e-68-0m488-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/05d3/3343872/4e649c252a71/e-68-0m488-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/05d3/3343872/4e649c252a71/e-68-0m488-fig1.jpg

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